H1 w/ AA is a call and take note about villain hand, even if he has a set , it's his mistake not yours. hand is played fine.

H2 w/ AQs, if you know he 3bet BTN more then QQ+,AK, the call is ok, if not , you should fold preflop. flop c/c is ok, so is turn i think, but river i am folding cause you are both very deep and i think he'd rather call TT, JJ then to raise AI. so i think in this spot w/ his line he has KK+.