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Thinking about it the opposite way round, if you want to have hands you bluff jam with (like A5s), you've got to consider what percentage of the time he 4bet-folds. That gives you the fold equity you get from jamming with A5s, then you want to put him in a situation where he can't effectively bluffcatch.
So, let's say his 4bet value range is [QQ+,AK], well his weakest hands (his bluffcatchers) are QQ and AK - they are the weakest hands in that range, and if he's going to call with QQ (or AK) when you jam, he is basically bluffcatching right?
So, if when he calls with QQ (or AK) he has just the right amount of equity vs. your overall jamming range (including A5s) that he breaks even doing that, he will be indifferent to calling - it won't matter whether he calls with QQ/AK or just folds, either way his EV is 0. Note that his EV is 0 after he's already put his 4bet in the pot - so the hand overall is not breakeven for him, but the situation once you jam is.
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