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I think we can call and get it in if we hit and the board doesn't pair.
Some math;
If we always fold when the board pairs, then we have 10 outs = 21.7%.
Pot odds are 62/222 = 27.9%, so we'll have to look at the implied.
He has 100$ left, which he has to call off [62/(222+100x)=0.217] ---> x = 63.7% of the time for us to break even. With the description that he overvalues his hands postflop I tend to think that he'll call off 100$ in a 322$ pot on the river more than that even if the obvious flush comes.
Also, we'll get to check behind and win the showdown some amount of the time when the board pairs, but I'm thinking we can then probably stick the last 100 in for value pretty safely?
All in all I think it's kinda marginal but a call is good.
I think I might like a flop call better than a raise against the described villain.
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